Webbridgehead: [noun] a fortification protecting the end of a bridge nearest an enemy. an area around the end of a bridge. WebTools. In organic chemistry, Bredt's rule is an empirical observation that states that a double bond cannot be placed at the bridgehead of a bridged ring system, unless the rings are large enough. The rule is named after Julius Bredt, who first discussed it in 1902 [1] and codified it in 1924. [2] It primarily relates to bridgeheads with carbon ...
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